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Leaving Barcelona, you'll head straight to Montserrat to visit the Royal Basilica where the famous 12th-century statue of the Black Virgin is housed. At 1pm on weekdays there is the opportunity to hear one of Europe's oldest children's choirs, La Escolania de Montserrat. While you're here there's time to visit the fascinating Museum of Montserrat, go for a walk or ride the rack railway or cable car up the mountain.
In the afternoon, leave Montserrat to visit one of the most famous wine producers of the Penedes region, either Freixenet or Codorniu. Visit their vast wine cellars, sample the product and see why this sparkling wine has acquired international fame.